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| Causes burns. May cause sensitization by skin contact. For potential danger for the environment, see section 12. |
| MATERIAL SAFETY DATA SHEET MSDS |
| Last changed: 05/05/99 | Internal num.: | Replaces date:04/21/94 |
| PRE - COMP. A |
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| No | Ingredients name | CAS-NO | Weight% | Dangerclas./Cmnt. | |
| 1 |
POLYAMINE ADDUCT |
- |
10-25% |
C,34-43 |
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| 2 |
ETHYLENE GLYCOL |
107-21-1 |
1-2,5% |
Xn,22 |
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| 3 |
2,4,7,9 TETRAMETYL-S-DECYNE-4,7-DIOL |
- |
1-2,5% |
Xi,36 |
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INGREDIENT COMMENTS
| Substances presenting a health hazard within the meaning of the CHIP Regulations or assigned occupational exposure limits. |
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| Causes burns. May cause sensitization by skin contact. For potential danger for the environment, see section 12. |
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GENERAL
| In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. |
INHALATION
| Remove to fresh air, keep the patient warm and at rest. If breathing has stopped, administer artificial respiration. Place in stable position on one side and keep warm with blankets etc. Seek medical advice. |
SKIN CONTACT
| Remove contaminated clothing. Wash skin thoroughly with soap and water or use a propietary skin cleaner. Do NOT use solvents or thinners. |
EYE CONTACT
| Remove any contact lenses. Holding the eyelids apart. Rinse with water for at least 1 hour. Seek medical advice. |
INGESTION
| DO NOT INDUCE VOMITING. If accidentally swallowed obtain immediate medical attention. Keep at rest. Seek medical advice. |
MEDICAL INFORMATION
| Regulary medical control. If allergic skin reactions persist, seek medical advice by a specialist. |
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PROPER FIREFIGHTING EQUIPMENT
| Recommended: alcohol resistant foam, CO2, powders, water spray. Not to be used: water jet. |
FIRE AND EXPLOSION HAZARDS
| Appropirate self-contained breathing apparatus may be required. Decomposition products may be a hazard to health. Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). |
PERSONAL PROTECTION WHEN FIREFIGHTING
| Professional fire-fighters are required to use an air-fed system when dealing with major fires. The personal protective equipment required is provided in section 8. |
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OTHER INFORMATION
| If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the Environmental Agency. Clean preferably with a detergent; avoid use of solvents. Do not allow to enter drains or watercourses. Place in container for disposal according to local regulations (see section 13). sand, earth, vermiculite and diatomaceous earth. g. Contain and collect spillage with non-combustible absorbent materials, e. Refer to protective measures listed in sections 7 and 8. Avoid breathing vapours. |
HANDLING ADVICE
| Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. For personal protective equipment see Section 8. Never use pressure to empty: the container is not a pressure vessel. Always keep in containers made of the same material as the supply container. The Manual Handling Operations Regulations may apply to the handling of containers of this product. |
STORAGE
| Observe the label precautions. Keep out of frost. Store in a dry, cold and well ventilated place away from sources of heat, ignition and direct sunlight. Store separately from oxidising agents, strongly alkaline and strongly acid materials. No smoking. Containers which are opened should be properly resealed and kept upright to prevent leakage. |
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OEL's:
| Ingredients name | CAS-no | OEL value | OEL |
| ETHYLENE GLYCOL |
107-21-1 |
10.0 mg\m3 |
EXPOSURE CONTROL
| Spray mist contains all substances of the product and must not be inhaled. OELs are taken from the current version of EH40 (by Health & Safety Executive, UK). Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Provide adequate ventilation. |
RESP. PROTECTION
| By other operations than spraying: In well-ventilated areas, air-fed respirators could be replaced by a combination of charcoal filter and particulate filter mask. Air-fed respiratory protective should be worn when this product is sprayed. |
EYE PROTECTION
| Eye protection designed to protect against liquid splashes should be worn. |
HAND PROTECTION
| Barrier creams should not be applied once exposure has occurred. Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. For prolonged or repeated contact, use nitrile or neoprene gloves. |
SKIN PROTECTION
| When spraying use suit covering the whole body. Wear anti-static clothing made of natural fibre or of heat-resistant synthetic fibre. |
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STABILITY
| Stable under recommended storage and handling conditions (see section 7). |
MATERIALS TO AVOID
| Keep away from oxidising agents, strongly alkaline and strongly acidic materials to prevent the exothermic reactions. |
HAZARDOUS DECOMPOSITION PRODUCTS
| In a fire , hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. |
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GENERAL
| There are no toxicological data available on the product itself. |
INHALATION
| Exposure to vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system. |
SKIN CONTACT
| Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. May cause sensitisation by skin contact. |
EYE CONTACT
| Splashed in the eyes may cause irritation and irreversible local damage. |
INGESTION
| Swallowing in connection with accidents can result in vomiting and stormach pains. |
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OTHER INFORMATION
| There is no data available on the product itself. |
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| Do not allow into drains or water courses Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. |
WASTEGROUP
| 08 01 02 waste paints and varnish free of halogenated solvents. 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVE, SEALANTS AND PRINTING INKS. |
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| Transport only in accordance with ADR for road, RID for rail and IMDG for sea transport. |
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| Classif.: |
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COMPOSITION
| POLYAMINE ADDUCT (10-25%) |
R-PHRASES
| R43 May cause sensitization by skin contact. R34 - Causes burns. |
S-PHRASES
| S46 If swallowed, seek medical advice immediately and show this container or label. S36/37/39 Wear suitable protection clothing, gloves and eyes/face protection. S26-In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S38 In case of insufficient ventilation, wear suitable respiratory equipment. S23 Do not breathe vapour/spray. S1/2 Keep locked up and out of the reach of children. |
REFERENCES
| The product is classified and labelled for supply in accordance with the current issue of CHIP Regulations, and the latest version of the approved supply list. |
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INFORMATION SOURCES:
VENDOR NOTES
| The information contained in this MSDS is based on the present state of knowledge and current national legislation. As the specific conditions of use of the product are outside the supplier's control, the user is responsible for ensuring that the requirements of relevant legislation are compiled with. The information in this MSDS provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. Further information and relevant advice can be found in: The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992:2839). The Control of Substances Hazardous to Health Regulations 1988 (SI1988:1657). The Highly Flammable Liquids and liquefied Petroleum Gases Regulations 197 (SI 1972:917). The Manual Handling Operations Regulations 1992 (SI 1992:2793). Storage of Flammable Liquids in Containers, HS(G)51. Storage of Packaged Dangerous Substances, HS(G)71. The selection, use and maintenance of respiratory protective equipment: A practical guide HS(G)53. |
USER NOTES