1. PRODUCT AND COMPANY
 
TRADE NAME :

PENGUIN DURAHART
SYNONYMS : PENGUIN DURAHART
APPLICATION : Antifouling based on special binder
PRODUCER/IMPORTER :
Company : JOTUN-HENRY CLARK LTD.
Address : Stather Road, Flixborough, Scunthorpe
Zip && city : North Lincolnshire DN15 8RR
Telephone : +44 1724 40 00 00
Fax : +44 1724 40 01 00
Emergencyphones : Contact the National Poison Center
Contactperson : QA/Environm. dept., JOTUN A/S, NORWAY
Responsible : QA/Environm. dept., JOTUN A/S, NORWAY
2. COMPOSITION OF PRODUCT
No Ingredients name CAS-NO Weight% Dangerclas./Cmnt.
1
 ROSIN
 8050-09-7
 10-30
 Xi;Sens,43
2
 XYLENE, mixed isomers
 1330-20-7
 2,5-10
 Xn,10-20/21-38
3
 WHITE SPIRIT, REG.(AROM. 17-22%)
 64742-82-1
 2,5-10
 XnN,10-65-51/53
4
 AROMATIC HYDROCARBONS C9-C12
 64742-95-6
 10-25
 XnN,10-37-65-51/53
5
 COPPER (I) OXIDE
 1317-39-1
 50-100
 Xn,22
Legend: T+=Very toxic, T=Toxic, C=Corrosive, Xn=Harmful, Xi=Irritant, IK=No classification required, E=Explosive, O=Oxidising, F+=Extremely flammable, F=Very flammable, Fo=Flammable, N=Dang. to the environment,

INGREDIENT COMMENTS

Substances presenting a health hazard within the meaning of the current issue of the CHIP Regulations or assigned occupational exposure limits.
3. HAZARD IDENTIFICATION
 Harmful 
Flammable. Harmful if swallowed. May cause sensitization by skin contact. For potential danger for the environment, see section 12.
4. FIRST AID

GENERAL

In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.

INHALATION

Remove to fresh air, keep the patient warm and at rest. If breathing has stopped, administer artificial respiration. If unconscious place in the recovery position. Seek medical advice.

SKIN CONTACT

Remove contaminated clothing. Wash skin thoroughly with soap and water or use an appropriate skin cleaner. Do NOT use solvents or thinners.

EYE CONTACT

Remove any contact lenses. Hold the eyelids apart. Irrigate copiously with clean, fresh water for at least 10 minutes. Seek medical advice if symptoms persist.

INGESTION

DO NOT INDUCE VOMITING. If accidentally swallowed obtain immediate medical attention. Keep at rest. Seek medical advice.
5. FIRE FIGHTING MEASURES

PROPER FIREFIGHTING EQUIPMENT

Not to be used: water jet. Recommended: alcohol resistant foam, CO2, powders, water spray.

FIRE AND EXPLOSION HAZARDS

Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Decomposition products may be a hazard to health. Appropriate self-contained breathing apparatus may be required.

PERSONAL PROTECTION WHEN FIREFIGHTING

The personal protective equipment required is provided in section 8. Professional fire-fighters are required to use an air-fed system when dealing with major fires.
6. ACCIDENTAL RELEASE MEASURES

OTHER INFORMATION

Exclude sources of ignition and ventilate the area. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Place in container for disposal according to local regulations (see section 13). Contain and collect spillage with non-combustible absorbent materials, e. g. sand, earth, vermiculite and diatomaceous earth. Do not allow to enter drains or watercourses. Clean preferably with a detergent; avoid use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the Environmental Agency.
7. HANDLING AND STORAGE

HANDLING ADVICE

The Manual Handling Operations Regulations may apply to the handling of containers of this product. Electrical equipment should be protected to appropriate standards. It is not a pressure vessel. Never use pressure to empty the container. Always keep in containers made of the same material as the supply container. For personal protection see Section 8. Smoking, eating and drinking are forbidden in the work area. Avoid inhalation of vapour and spray mist. Avoid skin and eye contact. Use non-sparking tools. Exclude sources of heat, sparks and open flame. Keep container tightly closed. Floors should be electrically conductive. Personnel should wear anti-static clothing and footwear. Always use earth (ground) wire when transferring from one container to another. The product may charge electrostatically. Use explosion-proof electrical equipment. The product should not be used in the vicinity of open flames or other sources of ignition. Prevent the formation of flammable or explosive mixtures and avoid vapour concentration higher than the occupational exposure limits. Vapours may form explosive mixtures with air. Vapours are heavier than air and may spread along the ground to sources of ignition.

STORAGE

Containers which have been opened must be carefully resealed and kept upright to prevent leakage. No smoking. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. Store in a dry, cold and well ventilated place away from sources of heat, ignition and direct sunlight. Observe precautions on container label. Store in accordance with regulations for flammable materials.
8. EXPOSURE CONTROL/PERSONAL PROTECTION

OEL's:

Ingredients name CAS-no OEL value OEL
XYLENE, mixed isomers
 1330-20-7
 441.0 mg/m3,Sk
662.0 mg/m3,Sk		 LTEL
STEL
WHITE SPIRIT, REG.(AROM. 17-22%)
 64742-82-1
 566.0 mg/m3
850.0 mg/m3		 LTEL
STEL
AROMATIC HYDROCARBONS C9-C12
 64742-95-6
 125.0 mg/m3
 LTEL

EXPOSURE CONTROL

Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Spray mist contains contains all substances of the product and must never be inhaled. OELs (Occupational Exposure Limits) are taken from the current version of EH40 (by Health & Safety Executive, UK).

RESP. PROTECTION

By other operations than spraying: In well-ventilated areas, air-fed respirators could be replaced by a combination of charcoal filter and particulate filter mask. Air-fed respiratory protective should be worn when spraying this product.

EYE PROTECTION

Eye protection designed to protect against liquid splashes should be worn.

HAND PROTECTION

Use nitrile or PVA gloves. Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. Barrier creams should not be applied once exposure has occurred.

SKIN PROTECTION

Wear anti-static clothing made of natural fibre or of heat-resistant synthetic fibre. When spraying use suit covering the whole body.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form: Liquid.
Colour: Various.
Odour: Organic solvent.
Solubility: Organic solvent.
 
Melting point/range: - Density: 1,60
Expl. limit LEL-UEL%: 0,90 - 7,0 - Boiling point/range: 138 - 198ºC
Flash point: 26ºC pH concentrate: -
Viscosity: 250 - 300 cP Ignition temp.: 240ºC
10. STABILITY AND REACTIVITY

STABILITY

Stable under recommended storage and handling conditions (see section 7).

MATERIALS TO AVOID

Keep away from oxidising agents, strongly alkaline and strongly acidic materials to prevent the exothermic reactions.

HAZARDOUS DECOMPOSITION PRODUCTS

In a fire , hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced.
11. TOXICOLOGICAL INFORMATION

GENERAL

There is no toxicological data available on the product itself.

INHALATION

Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous system. Symptoms and signs include headache; dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.

SKIN CONTACT

May cause sensitisation by skin contact. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin.

EYE CONTACT

Splashes in the eyes may cause irritation and reversible damage.

INGESTION

Accidental ingestion may cause vomiting and abdominal pain. Risk of chemical pneumonia by aspiration.
12. ECOLOGICAL INFORMATION

OTHER INFORMATION

There is no data available on the product itself. The product contains aromatic hydrocarbons C9-C12 labelled "Dangerous for the environment". The product contains white spirit, reg. (arom. 17-22) labelled "Dangerous for the environment".
13. DISPOSAL
Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Do not allow into drains or water courses.

WASTEGROUP

08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVE, SEALANTS AND PRINTING INKS. 08 01 02 waste paints and varnish free of halogenated solvents.
14. TRANSPORT INFORMATION
PROPER SHIPPING NAME PAINT
 
IMDG (Sea)
UN No 1263 Class 3.3
Packaging Group III EmS 3 - 05
MFAG 310 Marine Pollutant P
Page 3372
Not ADR-restricted ref. NOTE under E of marginal 2301 (applicable to receptacles of less than 450 litres capacity). Not regulated according to ADR, ref. marg. no. 2301 E (for containers < 450 ltr).
15. REGULATORY INFORMATION
Classif.:
 Harmful 

COMPOSITION

ROSIN (10-30), XYLENE, mixed isomers (2,5-10), WHITE SPIRIT, REG.(AROM. 17-22%) (2,5-10), AROMATIC HYDROCARBONS C9-C12 (10-25), COPPER (I) OXIDE (50-100)

R-PHRASES

R10 Flammable. R22 Harmful if swallowed. R43 May cause sensitization by skin contact.

S-PHRASES

S2 Keep out of reach of children. S23 Do not breathe vapour/spray. S24 Avoid contact with skin. S38 In case of insufficient ventilation, wear suitable respiratory equipment. S46 If swallowed, seek medical advice immediately and show this container or label.

REFERENCES

The product is classified and labelled for supply in accordance with the current issue of CHIP Regulations, and the latest version of the approved supply list.
16. OTHER INFORMATION

INFORMATION SOURCES:

VENDOR NOTES

The selection, use and maintenance of respiratory protective equipment: A practical guide HS(G)53. Storage of Packaged Dangerous Substances, HS(G)71. Storage of Flammable Liquids in Containers, HS(G)51. The Manual Handling Operations Regulations 1992 (SI 1992:2793). The Highly Flammable Liquids and liquefied Petroleum Gases Regulations 1972 (SI 1972:917). The Control of Substances Hazardous to Health Regulations 1988 (SI1988:1657). Further information and relevant advice can be found in: The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992:2839). The information in this MSDS provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. As the specific conditions of use of the product are outside the supplier's control, the user is responsible for ensuring that the requirements of relevant legislation are compiled with. The information contained in this MSDS is based on the present state of knowledge and current national legislation.

USER NOTES