(0) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 MATERIAL SAFETY DATA SHEET Index

MATERIAL SAFETY DATA SHEET MSDS

Last changed: 06/25/99

Internal num.: 01

Replaces date:08/19/99

PENGUIN RACING

1. PRODUCT AND COMPANY

TRADE NAME : PENGUIN RACING APPLICATION : Antifouling PRODUCER/IMPORTER : Company : JOTUN-HENRY CLARK LTD. Address : Flixborough, Scunthorpe Zip && city : North Lincolnshire DN15 8RR Telephone : +44 1724 40 00 00 Fax : +44 1724 40 01 00 Emergencyphones : Contact the National Poison Center Contactperson : QA/Environm. dept., JOTUN A/S, Norway Responsible : QA/Environm. dept., JOTUN A/S, Norway

2. COMPOSITION OF PRODUCT

No	Ingredients name	CAS-NO	Weight%	Dangerclas./Cmnt.
1	AROMATIC HYDROCARBONS, C9-C12	64742-95-6	10-25	Xn,N,10-37-65-51/53
2	COLOPHONY	8050-09-7	2,5-10	Xi;Sens,43
3	DICHLOFLUANID (ISO)	1085-98-9	2,5-10	Xi,36-43
4	DIKOPPEROXIDE	1317-39-1	25-50	Xn,22
5	2-METHOXY-1-METHYLETHYLACETAT	108-65-6	1-5	Xi,10-36
6	CUPROUS THIOCYANATE	000111-67-7	25-50	Xn,20/21/22-32
Legend: T+=Very toxic, T=Toxic, C=Corrosive, Xn=Harmful, Xi=Irritant, IK=No classification required, E=Explosive, O=Oxidising, F+=Extremely flammable, F=Very flammable, Fo=Flammable, N=Dang. to the environment,

INGREDIENT COMMENTS

Substances presenting a health hazard within the meaning of the current issue of the CHIP Regulations or assigned occupational exposure limits.

3. HAZARD IDENTIFICATION

Harmful

FLAMMABLE. HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED. IRRITATING TO RESPIRATORY SYSTEM. MAY CAUSE SENSITIZATION BY SKIN CONTACT. For potential danger for the environment, see section 12.

4. FIRST AID

GENERAL

In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.

INHALATION

Remove to fresh air, keep the patient warm and at rest. If breathing has stopped, administer artificial respiration. Place in stable position on one side and keep warm with blankets etc. Seek medical advice.

SKIN CONTACT

Remove contaminated clothing. Wash skin thoroughly with soap and water or use an appropriate skin cleaner. Do NOT use solvents or thinners.

EYE CONTACT

Remove any contact lenses. Hold the eyelids apart. Irrigate copiously with clean, fresh water for at least 10 minutes. Seek medical advice if symptoms persist.

INGESTION

DO NOT INDUCE VOMITING. If accidentally swallowed obtain immediate medical attention. Keep at rest. Seek medical advice.

MEDICAL INFORMATION

Risk of chemical pneumonia by aspiration. Keep attention: danger of lung damage. General health examination. Professional evaluation of the work station. Person developing a skin rash are to be directed to a dermatologist for exampnation.

5. FIRE FIGHTING MEASURES

PROPER FIREFIGHTING EQUIPMENT

Recommended: alcohol resistant foam, CO2, powders, water spray. Not to be used: water jet.

FIRE AND EXPLOSION HAZARDS

Decomposition products may be a hazard to health. Fire will produce dense black smoke containing hazardous products of combustion (see Section 10).

PERSONAL PROTECTION WHEN FIREFIGHTING

The personal protective equipment required is provided in section 8. Professional fire-fighters are required to use an air-fed system when dealing with major fires.

OTHER INFORMATION

Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to fire with water.

6. ACCIDENTAL RELEASE MEASURES

OTHER INFORMATION

Exclude sources of ignition and ventilate the area. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Place in container for disposal according to local regulations (see section 13). Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite and diatomaceous earth. Do not allow to enter drains or watercourses. Clean preferably with a detergent; avoid use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the Environmental Agency.

7. HANDLING AND STORAGE

HANDLING ADVICE

The Manual Handling Operations Regulations may apply to the handling of containers of this product. Electrical equipment should be protected to appropriate standards. Never use pressure to empty: the container is not a pressure vessel. Always keep in containers made of the same material as the supply container. For personal protective equipment see Section 8. Smoking, eating and drinking are forbidden in the work area. Avoid inhalation of vapour and spray mist. Avoid skin and eye contact. Use non-sparking tools. Keep container tightly closed. Exclude sources of heat, sparks and open flame. Floors should be electrically conductive. Personnel should wear anti-static clothing and footwear. Allways use earth (ground) wire when transferring from one container to another. The product may charge electrostatically. Use explosion-proof electrical equipment. The product should not be used in vicinity of open flames or other sources of ignition. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. Vapours may form explosive mixtures with air. Vapours are heavier than air and may spread along floors.

STORAGE

Containers which are opened should be properly resealed and kept upright to prevent leakage. No smoking. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. Store in a dry, cold and well ventilated place away from sources of heat, ignition and direct sunlight. Observe the label precautions. Store in accordance with the regulations for flammable materials.

8. EXPOSURE CONTROL/PERSONAL PROTECTION

OEL's:

Ingredients name	CAS-no	OEL value	OEL
AROMATIC HYDROCARBONS, C9-C12	64742-95-6	125.0 mg/m3	LTEL

EXPOSURE CONTROL

Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Spray mist contains all substances of the product and must not be inhaled. OELs are taken from the current version of EH40 (by Health & Safety Executive, UK).

RESP. PROTECTION

Gas mask with filter A (brown, organic substances) may be necessary. Gas mask with combined filter (gas filter A2/dust filter P2) may be necessary when spraying.

EYE PROTECTION

Eye protection designed to protect against liquid splashes should be worn.

HAND PROTECTION

Use nitrile/PVA gloves. Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. Barrier creams should not be applied once exposure has occurred.

SKIN PROTECTION

Wear anti-static clothing made of natural fibre or of heat resistant synthetic fibre. When spraying use suit covering the whole body.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form: Liquid. Colour: Various. Odour: Organic solvent. Solubility: Organic solvent.

Melting point/range: - Density: 1.70 Expl. limit LEL-UEL%: 1,00 - 6,0 - Boiling point/range: 145 - 177ºC Flash point: 28ºC pH concentrate: - Viscosity: 300 cP Ignition temp.: 500ºC

10. STABILITY AND REACTIVITY

STABILITY

Stable under recommended storage and handling conditions (see section 7).

MATERIALS TO AVOID

Keep away from oxidising agents, strongly alkaline and strongly acidic materials to prevent the exothermic reactions. Contact with acid liberates very toxic gas.

HAZARDOUS DECOMPOSITION PRODUCTS

In a fire , hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced.

11. TOXICOLOGICAL INFORMATION

GENERAL

There are no toxicological data available on the product itself.

INHALATION

Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous system. Symptoms and signs include headache; dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.

SKIN CONTACT

Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. May cause sensitisation by skin contact.

EYE CONTACT

Splashes in the eyes may cause irritation and reversible local damage.

INGESTION

Swallowing in connection with accidents can result in vomiting and stomach pain. Chemical pneumonia can occur if solvents are inhaled.

12. ECOLOGICAL INFORMATION

OTHER INFORMATION

There is no data available on the product itself. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. The product contains aromatic hydrocarbons C9-C12 labelled "Dangerous for the environment".

13. DISPOSAL

Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Do not allow into drains or water courses. Waste must be disposed of at approved landfill/waste storage or traement facility.

WASTEGROUP

08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVE, SEALANTS AND PRINTING INKS.

14. TRANSPORT INFORMATION

PROPER SHIPPING NAME PAINT

IMDG (Sea) UN No 1263 Class 3.3 Label 3 Packaging Group III EmS 3 - 05 MFAG 310 Page 3372

Transport only in accordance with ADR for road, RID for rail and IMDG for sea transport. Not ADR-restricted ref. NOTE under E of marginal 2301 (applicable to receptacles of less than 450 litres capacity).

15. REGULATORY INFORMATION

Classif.:

Harmful

COMPOSITION

AROMATIC HYDROCARBONS, C9-C12 (10-25), COLOPHONY (2,5-10), DICHLOFLUANID (ISO) (2,5-10), DIKOPPEROXIDE (25-50), 2-METHOXY-1-METHYLETHYLACETAT (1-5), CUPROUS THIOCYANATE (25-50)

R-PHRASES

R10 Flammable. R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed. R37 Irritating to respiratory system. R43 May cause sensitization by skin contact.

S-PHRASES

S2 Keep out of reach of children. S23 Do not breathe vapour/spray. S36/37 Wear suitable protective clothing and gloves. S38 In case of insufficient ventilation, wear suitable respiratory equipment. S42 During spraying wear suitable respiratory equipment. S46 If swallowed, seek medical advice immediately and show this container or label.

REFERENCES

EU-directive 67/548 and 88/379. The product is classified and labelled for supply in accordance with the current issue of CHIP Regulations, and the latest version of the approved supply list.

16. OTHER INFORMATION

ISSUED:

25/06/99

INFORMATION SOURCES:

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