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MATERIAL SAFETY DATA SHEET MSDS

Last changed: 06/25/99

Internal num.: 13

Replaces date:08/19/98

PENGUIN GELCOATSPARKEL - COMP B

1. PRODUCT AND COMPANY

TRADE NAME : PENGUIN GELCOATSPARKEL - Comp. B APPLICATION : Two-pack polyesterfiller PRODUCER/IMPORTER : Company : JOTUN-HENRY CLARK LTD. Address : Flixborough, Scunthorpe Zip && city : North Lincolnshire DN15 8RR Telephone : +44 1724 40 00 00 Fax : +44 1724 40 01 00 Emergencyphones : Contact the National Poison Center Contactperson : QA/Environm. dept., JOTUN A/S, NORWAY Responsible : QA/Environm. dept., JOTUN A/S, NORWAY

2. COMPOSITION OF PRODUCT

No	Ingredients name	CAS-NO	Weight%	Dangerclas./Cmnt.
1	ACETYLACETONE PEROXIDE	37187-22-7	25-50	C,O,R5-8-34
2	DIACETONE ALCOHOL	123-42-2	50-100	Xi,R-36
Legend: T+=Very toxic, T=Toxic, C=Corrosive, Xn=Harmful, Xi=Irritant, IK=No classification required, E=Explosive, O=Oxidising, F+=Extremely flammable, F=Very flammable, Fo=Flammable, N=Dang. to the environment,

INGREDIENT COMMENTS

Substances presenting a health hazard within the meaning of the current issue of the CHIP Regulations or assigned occupational exposure limits.

3. HAZARD IDENTIFICATION

Corrosive   Oxidizing

CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE. CAUSES BURNS. RISK OF EXPLOSION IF HEATED UNDER CONFINEMENT. For potential danger for the environment, see section 12.

4. FIRST AID

GENERAL

In all cases of doubt, or when symptoms persist, seek medical attention. Obtain advice via telephone; before the patient is transported to a doctor or hospital. Never give anything by mouth to an unconscious person.

INHALATION

Remove to fresh air, keep the patient warm and at rest. If breathing has stopped, administer artificial respiration. Place in stable position on one side and keep warm with blankets etc. Seek medical advice.

SKIN CONTACT

Remove contaminated clothing. Wash skin thoroughly with soap and water or use an appropriate skin cleaner. Flush the skin with plenty of water in at least 30 minutes.

EYE CONTACT

Remove any contact lenses. Hold the eyelids apart. Rinse with water for at least 20 minutes. Seek medical advice.

INGESTION

DO NOT INDUCE VOMITING. Rinse the mouth with large amounts of water if the patient is conscious. Keep at rest. Seek medical advice.

MEDICAL INFORMATION

Obtain miedical surveillance concerning burn injuries in mouth and throat. Aspiration hazard by vomiting. All poisoned persons should be transported in recovery position. An authorised person should acompany under the transport. Stomach-rinsing may bee considered, for instance with an antioxydant. Eye injuries should be treated with chloramphenicol or antiseptic eye treatment. Local anesthetica may be given to relieve pain. Eye specialist should be consulted as soon as possible.

5. FIRE FIGHTING MEASURES

PROPER FIREFIGHTING EQUIPMENT

Recommended: alcohol resistant foam, CO2, powders, water spray. Not to be used: water jet.

FIRE AND EXPLOSION HAZARDS

Decomposition products may be a hazard to health. Fire will produce dense black smoke containing hazardous products of combustion (see Section 10).

PERSONAL PROTECTION WHEN FIREFIGHTING

The personal protective equipment required is provided in section 8. Professional fire-fighters are required to use an air-fed system when dealing with major fires.

6. ACCIDENTAL RELEASE MEASURES

OTHER INFORMATION

If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the Environmental Agency. Clean preferably with a detergent; avoid use of solvents. Do not allow to enter drains or watercourses. Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite and diatomaceous earth. Place in container for disposal according to local regulations (see section 13). Refer to protective measures listed in sections 7 and 8. Avoid breathing vapours. Exclude sources of ignition and ventilate the area.

7. HANDLING AND STORAGE

HANDLING ADVICE

The product should not be used in vicinity of open flames or other sources of ignition. Use explosion-proof electrical equipment. The product may charge electrostatically. Allways use earth (ground) wire when transferring from one container to another. Personnel should wear anti-static clothing and footwear. Floors should be electrically conductive. Keep container tightly closed. Exclude sources of heat, sparks and open flame. Use non-sparking tools. Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. Smoking, eating and drinking are forbidden in the work area. For personal protective equipment see Section 8. Always keep in containers made of the same material as the supply container. Never use pressure to empty: the container is not a pressure vessel. Electrical equipment should be protected to appropriate standards. The Manual Handling Operations Regulations may apply to the handling of containers of this product.

STORAGE

Store in accordance with the regulations for flammable materials. Observe the label precautions. Store in a dry, cold and well ventilated place away from sources of heat, ignition and direct sunlight. Store separately from reducing agents (i.e. amins), acids, alkalines og metal compounds. No smoking. Containers which are opened should be properly resealed and kept upright to prevent leakage.

8. EXPOSURE CONTROL/PERSONAL PROTECTION

EXPOSURE CONTROL

Spray mist contains all substances of the product and must not be inhaled. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Provide adequate ventilation.

RESP. PROTECTION

By other operations than spraying: In well-ventilated areas, air-fed respirators could be replaced by a combination of charcoal filter and particulate filter mask. Air-fed respiratory protective should be worn when this product is sprayed.

EYE PROTECTION

Eye protection designed to protect against liquid splashes should be worn.

HAND PROTECTION

Barrier creams should not be applied once exposure has occurred. Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. Use nitrile or neoprene gloves.

SKIN PROTECTION

Wear anti-static clothing made of natural fibre or of heat resistant synthetic fibre.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form: Liquid. Colour: Colourless. Odour: Faint. Solubility: Miscible with: Organic solvent. Water.

Melting point/range: -10 °C Density: 1,055 Expl. limit LEL-UEL%: - - Vapor pressure: 0,1 kPa Flash point: 63 °C pH concentrate: - Viscosity: 21 mPas at 20°C Ignition temp.: >380 °C

10. STABILITY AND REACTIVITY

STABILITY

Stable under recommended storage and handling conditions (see section 7).

MATERIALS TO AVOID

Keep away from oxidising agents, strongly alkaline and strongly acidic materials to prevent the exothermic reactions.

HAZARDOUS DECOMPOSITION PRODUCTS

In a fire , hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced.

11. TOXICOLOGICAL INFORMATION

GENERAL

This product contains phlegmatisizer which reduce the products flammability compared to pure peroxid. There are no toxicological data available on the product itself.

INHALATION

Symptoms and signs include headache; dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous system. Peroxides may cause irritation to respiratory system. Ketone peroxides can in extreme cases cause serious damage to the respiratory system.

SKIN CONTACT

Ketone peroxides og benzoyl peroxides may cause allergic eczema. Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin.

EYE CONTACT

Splashes in the eyes may cause serious damage to eyes.

12. ECOLOGICAL INFORMATION

OTHER INFORMATION

There is no data available on the product itself.

13. DISPOSAL

Do not allow into drains or water courses. Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act.

14. TRANSPORT INFORMATION

PROPER SHIPPING NAME ORGANIC PEROXIDE TYPE D, LIQUID

ADR (Road) UN No 3105 Class 5.2,5(b) IMDG (Sea) UN No 3105 Class 5,2 Packaging Group II EmS 5.2-01 MFAG 735 Page 5225

Transport only in accordance with ADR for road, RID for rail and IMDG for sea transport.

15. REGULATORY INFORMATION

Classif.:

Corrosive   Oxidizing

COMPOSITION

ACETYLACETONE PEROXIDE (25-50), DIACETONE ALCOHOL (50-100)

R-PHRASES

R5 Heating may cause an explosion. R8 Contact with combustible material may cause fire. R34 - Causes burns.

S-PHRASES

S50 Do not mix with peroxide acceleratores or with reducing agents. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S36/37/39 Wear suitable protection clothing, gloves and eyes/face protection. S26-In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S14 Keep away from reducing materials, heavy metal compounds, acids and bases. S3/7 Keep container tightly closed in a cool place. S1/2 Keep locked up and out of the reach of children.

REFERENCES

The product is classified and labelled for supply in accordance with the current issue of CHIP Regulations, and the latest version of the approved supply list.

16. OTHER INFORMATION

ISSUED:

25/06/98

INFORMATION SOURCES:

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