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| FLAMMABLE. IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. For potential danger for the environment, see section 12. |
| MATERIAL SAFETY DATA SHEET MSDS |
| Last changed: 06/29/99 | Internal num.: 01 | Replaces date:06/01/97 |
| REPRIN SPESIAL |
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| No | Ingredients name | CAS-NO | Weight% | Dangerclas./Cmnt. | |
| 1 |
AROMATIC HYDROCARBONS, C9-C12 |
64742-95-6 |
25-50 |
XnN,10-37-65-51/53 |
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| 2 |
1-METOXY-2-PROPANOL |
107-98-2 |
25-50 |
10 |
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| 3 |
N-METHYL-2-PYRROLIDONE |
872-50-4 |
10-25 |
Xi,36/38 |
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INGREDIENT COMMENTS
| Substances presenting a health hazard within the meaning of the current issue of the CHIP Regulations or assigned occupational exposure limits. |
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| FLAMMABLE. IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN. For potential danger for the environment, see section 12. |
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GENERAL
| In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. |
INHALATION
| Remove to fresh air, keep the patient warm and at rest. If breathing has stopped, administer artificial respiration. Place in stable position on one side and keep warm with blankets etc. Seek medical advice. |
SKIN CONTACT
| Remove contaminated clothing. Wash skin thoroughly with soap and water or use an appropriate skin cleaner. Do NOT use solvents or thinners. |
EYE CONTACT
| Remove any contact lenses. Hold the eyelids apart. Irrigate copiously with clean, fresh water for at least 10 minutes. Seek medical advice if symptoms persist. |
INGESTION
| DO NOT INDUCE VOMITING. If accidentally swallowed obtain immediate medical attention. Keep at rest. Seek medical advice. |
MEDICAL INFORMATION
| Risk of chemical pneumonia by aspiration. Keep attention: danger of lung damage. General health examination. Professional evaluation of the work station. |
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PROPER FIREFIGHTING EQUIPMENT
| Recommended: alcohol resistant foam, CO2, powders, water spray. Not to be used: water jet. |
FIRE AND EXPLOSION HAZARDS
| Decomposition products may be a hazard to health. Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). |
PERSONAL PROTECTION WHEN FIREFIGHTING
| The personal protective equipment required is provided in section 8. Professional fire-fighters are required to use an air-fed system when dealing with major fires. |
OTHER INFORMATION
| Do not allow run-off from fire fighting to enter drains or water courses. Cool closed containers exposed to fire with water. |
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OTHER INFORMATION
| Exclude sources of ignition and ventilate the area. Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Place in container for disposal according to local regulations (see section 13). Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite and diatomaceous earth. Do not allow to enter drains or watercourses. Clean preferably with a detergent; avoid use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the Environmental Agency. |
HANDLING ADVICE
| The Manual Handling Operations Regulations may apply to the handling of containers of this product. Electrical equipment should be protected to appropriate standards. Never use pressure to empty: the container is not a pressure vessel. Always keep in containers made of the same material as the supply container. For personal protective equipment see Section 8. Smoking, eating and drinking are forbidden in the work area. Avoid inhalation of vapour and spray mist. Avoid skin and eye contact. Use non-sparking tools. Keep container tightly closed. Exclude sources of heat, sparks and open flame. Floors should be electrically conductive. Personnel should wear anti-static clothing and footwear. Allways use earth (ground) wire when transferring from one container to another. The product may charge electrostatically. Use explosion-proof electrical equipment. The product should not be used in vicinity of open flames or other sources of ignition. Prevent the creation of flammable or explosive concentrations of vapour in air and avoid vapour concentration higher than the occupational exposure limits. Vapours may form explosive mixtures with air. Vapours are heavier than air and may spread along floors. |
STORAGE
| Containers which are opened should be properly resealed and kept upright to prevent leakage. No smoking. Store separately from oxidising agents and strongly alkaline and strongly acidic materials. Store in a dry, cold and well ventilated place away from sources of heat, ignition and direct sunlight. Observe the label precautions. Store in accordance with the regulations for flammable materials. |
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OEL's:
| Ingredients name | CAS-no | OEL value | OEL |
| AROMATIC HYDROCARBONS, C9-C12 |
64742-95-6 |
125.0 mg/m3 |
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| 1-METOXY-2-PROPANOL |
107-98-2 |
375.0 mg/m3,Sk 1120.0 mg/m3,Sk |
LTEL STEL |
| N-METHYL-2-PYRROLIDONE |
872-50-4 |
103.0 mg/m3,Sk 309.0 mg/m3,Sk |
LTEL STEL |
EXPOSURE CONTROL
| Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and solvent vapours below the OELs, suitable respiratory protection should be worn. Spray mist contains all substances of the product and must not be inhaled. OELs are taken from the current version of EH40 (by Health & Safety Executive, UK). |
RESP. PROTECTION
| Air-fed respiratory protective should be worn when this product is sprayed. By other operations than spraying: In well-ventilated areas, air-fed respirators could be replaced by a combination of charcoal filter and particulate filter mask. |
EYE PROTECTION
| Eye protection designed to protect against liquid splashes should be worn. |
HAND PROTECTION
| For prolonged or repeated contact, use PVA/EVOH gloves. Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. Barrier creams should not be applied once exposure has occurred. |
SKIN PROTECTION
| Wear anti-static clothing made of natural fibre or of heat resistant synthetic fibre. When spraying use suit covering the whole body. |
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STABILITY
| Stable under recommended storage and handling conditions (see section 7). |
MATERIALS TO AVOID
| Keep away from oxidising agents, strongly alkaline and strongly acidic materials to prevent the exothermic reactions. |
HAZARDOUS DECOMPOSITION PRODUCTS
| In a fire , hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. |
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GENERAL
| There are no toxicological data available on the product itself. |
INHALATION
| Exposure to organic solvent vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system and adverse effects on the renal and central nervous system. Symptoms and signs include headache; dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness. |
SKIN CONTACT
| Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. |
EYE CONTACT
| Splashes in the eyes may cause irritation and reversible local damage. |
INGESTION
| Swallowing in connection with accidents can result in vomiting and stomach pain. Chemical pneumonia can occur if solvents are inhaled. |
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OTHER INFORMATION
| There is no data available on the product itself. The product contains aromatic hydrocarbons C9-C12 labelled "Dangerous for the environment". |
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| Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Do not allow into drains or water courses. Waste must be disposed of at approved landfill/waste storage or traement facility. |
WASTEGROUP
| 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVE, SEALANTS AND PRINTING INKS. 08 01 02 waste paints and varnish free of halogenated solvents. |
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| Transport only in accordance with ADR for road, RID for rail and IMDG for sea transport. Not ADR-restricted ref. NOTE under E of marginal 2301 (applicable to receptacles of less than 450 litres capacity). |
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| Classif.: |
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COMPOSITION
R-PHRASES
| R10 Flammable. R36/37/38 - Irritating to eyes, respiratory system and skin. |
S-PHRASES
| S2 Keep out of reach of children. S23 Do not breathe vapour/spray. S38 In case of insufficient ventilation, wear suitable respiratory equipment. S46 If swallowed, seek medical advice immediately and show this container or label. |
REFERENCES
| The product is classified and labelled for supply in accordance with the current issue of CHIP Regulations, and the latest version of the approved supply list. |
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INFORMATION SOURCES:
VENDOR NOTES
| The selection, use and maintenance of respiratory protective equipment: A practical guide HS(G)53. Storage of Packaged Dangerous Substances, HS(G)71. Storage of Flammable Liquids in Containers, HS(G)51. The Manual Handling Operations Regulations 1992 (SI 1992:2793). The Highly Flammable Liquids and liquefied Petroleum Gases Regulations 197 (SI 1972:917). The Control of Substances Hazardous to Health Regulations 1988 (SI1988:1657). Further information and relevant advice can be found in: The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992:2839). and should not be construed as any guarantee of technical performance or suitability for particular applications. The information in this MSDS provides guidance on health, safety and environmental aspects of the product As the specific conditions of use of the product are outside the supplier's control, the user is responsible for ensuring that the requirements of relevant legislation are compiled with. The information contained in this MSDS is based on the present state of knowledge and current national legislation. |
USER NOTES