| MATERIAL SAFETY DATA SHEET MSDS |
| Last changed: 07/01/99 | Internal num.: 02 | Replaces date:06/30/98 |
| FORMEL V |
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| No | Ingredients name | CAS-NO | Weight% | Dangerclas./Cmnt. | |
| 1 |
2-BUTOXYETHANOL |
111-76-2 |
1-2,5 |
XnXi,20/21/22-37 |
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| 2 |
N-METHYL-2-PYRROLIDONE |
872-50-4 |
2,5-10 |
Xi,36/38 |
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| 3 |
ETHYLDIGLYCOL |
111-90-0 |
1-2,5 |
Xi,36 |
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INGREDIENT COMMENTS
| Substances presenting a health hazard within the meaning of the current issue of the CHIP Regulations or assigned occupational exposure limits. |
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| There are no riskphrases given for this product according to EU-legislation. For potential danger for the environment, see section 12. |
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GENERAL
| In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person. |
INHALATION
| Remove to fresh air, keep the patient warm and at rest. If breathing has stopped, administer artificial respiration. Place in stable position on one side and keep warm with blankets etc. Seek medical advice. |
SKIN CONTACT
| Remove contaminated clothing. Wash skin thoroughly with soap and water or use an appropriate skin cleaner. Do NOT use solvents or thinners. |
EYE CONTACT
| Remove any contact lenses. Hold the eyelids apart. Irrigate copiously with clean, fresh water for at least 10 minutes. Seek medical advice if symptoms persist. |
INGESTION
| DO NOT INDUCE VOMITING. If accidentally swallowed obtain immediate medical attention. Keep at rest. Seek medical advice. |
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PROPER FIREFIGHTING EQUIPMENT
| Not to be used: water jet. Recommended: alcohol resistant foam, CO2, powders, water spray. |
FIRE AND EXPLOSION HAZARDS
| Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). Decomposition products may be a hazard to health. |
PERSONAL PROTECTION WHEN FIREFIGHTING
| The personal protective equipment required is provided in section 8. Professional fire-fighters are required to use an air-fed system when dealing with major fires. |
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OTHER INFORMATION
| Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite and diatomaceous earth. Place in container for disposal according to local regulations (see section 13). Do not allow to enter drains or watercourses. Clean preferably with a detergent; avoid use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the Environmental Agency. |
HANDLING ADVICE
| The Manual Handling Operations Regulations may apply to the handling of containers of this product. Always keep in containers made of the same material as the supply container. Never use pressure to empty: the container is not a pressure vessel. For personal protective equipment see Section 8. Avoid inhalation of vapour and spray mist. Avoid skin and eye contact. |
STORAGE
| Containers which are opened should be properly resealed and kept upright to prevent leakage. No smoking. Store separately from oxidising agents, strongly alkaline and strongly acid materials. Observe the label precautions. Store in a dry, cold and well ventilated place away from sources of heat, ignition and direct sunlight. Keep out of frost. |
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OEL's:
| Ingredients name | CAS-no | OEL value | OEL |
| 2-BUTOXYETHANOL |
111-76-2 |
123.0 mg/m3, Sk |
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| N-METHYL-2-PYRROLIDONE |
872-50-4 |
103.0 mg/m3,Sk 309.0 mg/m3,Sk |
LTEL STEL |
EXPOSURE CONTROL
| Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Spray mist contains all substances of the product and must not be inhaled. |
RESP. PROTECTION
| Dust filter P2 may be necessary when spraying the product. |
EYE PROTECTION
| Eye protection designed to protect against liquid splashes should be worn. |
HAND PROTECTION
| Use nitrile or neoprene gloves. Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. Barrier creams should not be applied once exposure has occurred. |
SKIN PROTECTION
| Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. When spraying use suit covering the whole body. |
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STABILITY
| Stable under recommended storage and handling conditions (see section 7). |
MATERIALS TO AVOID
| Keep away from oxidising agents, strongly alkaline and strongly acidic materials to prevent the exothermic reactions. |
HAZARDOUS DECOMPOSITION PRODUCTS
| In a fire , hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. |
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GENERAL
| There are no toxicological data available on the product itself. |
INHALATION
| Exposure to vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system. |
SKIN CONTACT
| Repeated or prolonged contact with the product may lead to removal of natural fats from the skin resulting in non-allergic contact dermatitis and absorption through the skin. |
EYE CONTACT
| Splashes in the eyes may cause irritation and reversible local damage. |
INGESTION
| Swallowing in connection with accidents can result in vomiting and stomach pain. |
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OTHER INFORMATION
| There is no data available on the product itself. |
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| Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. Do not allow into drains or water courses. |
WASTEGROUP
| 08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVE, SEALANTS AND PRINTING INKS. 08 01 03 waste from water-based paints and varnishes. |
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| The product is not classified as dangerous goods for carriage. ADR for road, RID for rail and IMDG for sea transport. Transport only in accordance with |
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| Classif.: |
COMPOSITION
S-PHRASES
| S2 Keep out of reach of children. S23 Do not breathe vapour/spray. S38 In case of insufficient ventilation, wear suitable respiratory equipment. |
REFERENCES
| The product is classified and labelled for supply in accordance with the current issue of CHIP Regulations, and the latest version of the approved supply list. |
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INFORMATION SOURCES:
VENDOR NOTES
| The selection, use and maintenance of respiratory protective equipment: A practical guide HS(G)53. Storage of Flammable Liquids in Containers, HS(G)51. The Highly Flammable Liquids and liquefied Petroleum Gases Regulations 1972 (SI 1972:917). Storage of Packaged Dangerous Substances, HS(G)71. The Manual Handling Operations Regulations 1992 (SI 1992:2793). The Control of Substances Hazardous to Health Regulations 1988 (SI1988:1657). The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992:2839). Further information and relevant advice can be found in: and should not be construed as any guarantee of technical performance or suitability for particular applications. The information in this MSDS provides guidance on health, safety and environmental aspects of the product As the specific conditions of use of the product are outside the supplier's control, the user is responsible for ensuring that the requirements of relevant legislation are compiled with. The information contained in this MSDS is based on the present state of knowledge and current national legislation. |
USER NOTES