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| HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED. CAUSES BURNS. MAY CAUSE SENSITIZATION BY SKIN CONTACT. For potential danger for the environment, see section 12. |
| MATERIAL SAFETY DATA SHEET MSDS |
| Last changed: 02/09/1999 | Internal num.: 02 | Replaces date:22/04/1996 |
| PRIMASTIC - COMP. B |
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| No | Ingredients name | CAS-NO | Weight% | Dangerclas./Cmnt. | |
| 1 | 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE | 2855-13-2 | 10-25 | Xn,C,21/22-34-43-52/53 | |
| 2 | BENZYLALCOHOL | 100-51-6 | 25-50 | Xn,20/22 | |
| 3 | 2-METYL-1,5-PENTAMETYLENDIAMIN | - | 10-25 | C,20/22-34 | |
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| Substances presenting a health hazard within the meaning of the current issue of the CHIP Regulations or assigned occupational exposure limits. |
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| HARMFUL BY INHALATION, IN CONTACT WITH SKIN AND IF SWALLOWED. CAUSES BURNS. MAY CAUSE SENSITIZATION BY SKIN CONTACT. For potential danger for the environment, see section 12. |
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| In all cases of doubt, or when symptoms persist, seek medical attention. Obtain advice via telephone; before the patient is transported to a doctor or hospital. Never give anything by mouth to an unconscious person. |
| Keep the patient warm in a quiet place with fresh air. If breathing has stopped, administer artificial respiration. If unconscious place in the recovery position. Seek medical advice. |
| Remove contaminated clothing. Wash skin thoroughly with soap and water or use an appropriate skin cleaner. Do NOT use solvents or thinners. Flush the skin with plenty of water. |
| Remove any contact lenses. Hold the eyelids apart. Rinse with lukewarm water for 1 hour. Seek medical advice. |
| DO NOT INDUCE VOMITING. Drink water or milk/cream immediately. If accidentally swallowed obtain immediate medical attention. Keep at rest. Seek medical advice. |
| Regulary medical control. Person developing a skin rash are to be directed to a dermatologist for exampnation. Obtain miedical surveillance concerning burn injuries in mouth and throat. Aspiration hazard by vomiting. All poisoned persons should be transported in recovery position. An authorised person should acompany under the transport. Stomach-rinsing may bee considered, for instance with an antioxydant. Eye injuries should be treated with chloramphenicol or antiseptic eye treatment. Local anesthetica may be given to relieve pain. Eye specialist should be consulted as soon as possible. |
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| Recommended: alcohol resistant foam, CO2, powders, water spray. Not to be used: water jet. |
| Decomposition products may be a hazard to health. Fire will produce dense black smoke containing hazardous products of combustion (see Section 10). |
| The personal protective equipment required is provided in section 8. Professional fire-fighters are required to use an air-fed system when dealing with major fires. |
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| Avoid breathing vapours. Refer to protective measures listed in sections 7 and 8. Contain and collect spillage with non-combustible absorbent materials, e.g. sand, earth, vermiculite and diatomaceous earth. Place in container for disposal according to local regulations (see section 13). Do not allow to enter drains or watercourses. Clean preferably with a detergent; avoid use of solvents. If the product enters drains or sewers, the local water company should be contacted immediately; in the case of contamination of streams, rivers or lakes, the Environmental Agency. |
| Avoid skin and eye contact. Avoid inhalation of vapour and spray mist. For personal protective equipment see Section 8. Never use pressure to empty the container, it is not a pressure vessel. Always keep in containers made of the same material as the supply container. The Manual Handling Operations Regulations may apply to the handling of containers of this product. |
| Keep out of frost. Store in a dry, cold and well ventilated place away from sources of heat, ignition and direct sunlight. Observe the label precautions. Keep away from oxidizing materials, strongly alkaline materials and strong acids. No smoking. Containers which are opened should be properly resealed and kept upright to prevent leakage. |
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| Ingredients name | CAS-no | OEL value | OEL |
EXPOSURE CONTROL
| Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. Spray mist contains all substances of the product and must not be inhaled. OELs are taken from the current version of EH40 (by Health & Safety Executive, UK). |
| When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Air-fed respiratory protective equipment should be worn when spraying this product. When spraying, use also K-filter. |
| Eye protection designed to protect against liquid splashes should be worn. |
| Use butyl rubber/ viton gloves. Barrier creams may help to protect exposed areas of the skin but are not substitutes for full physical protection. Never apply barrier ceam to contaminated skin. |
| Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner.When spraying use suit covering the whole body. |
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| Stable under recommended storage and handling conditions (see section 7). |
| Keep away from oxidising agents, strongly alkaline and strongly acidic materials to prevent the exothermic reactions. |
| In a fire , hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced. |
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| There are no toxicological data available on the product itself. |
| Exposure to vapours may result in adverse health effects such as irritation of the mucous membrane and the respiratory system. |
| Products containing amines irritate the skin and may lead to allegic ecema. The allergic response may occur after a short periode of contact. Prolonged contact may cause burn damage. |
| May cause irreversible eye damage. Severe eye irritation Corrosive. |
| May cause burn damage to mucous membrane, esophagus and stomach. Accidental ingestion may cause vomiting and abdominal pains. |
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| The product contains components which are harmful for the environment, see point 2. The product should not be allowed to enter drains or water courses or be deposited where it can affect ground or surface waters. |
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| Wastes, including emptied containers, are controlled wastes and should be disposed of in accordance with regulations made under the Control of Pollution Act and the Environmental Protection Act. |
| 08 00 01 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (MFSU) OF COATINGS (PAINTS, VARNISHES AND VITREOUS ENAMELS), ADHESIVE, SEALANTS AND PRINTING INKS. 08 01 02 Waste paints and varnish free of halogenated solvents. |
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| Transport only in accordance with. ADR for road, RID for rail and IMDG for sea transport. |
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| Classif.: |
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| 3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE (10-25), BENZYLALCOHOL (25-50), 2-METYL-1,5-PENTAMETYLENDIAMIN (10-25) |
| R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.R43 May cause sensitization by skin contact. R34 - Causes burns. |
| S23 Do not breathe vapour/spray. S26-In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protection clothing, gloves and eyes/face protection. S38 In case of insufficient ventilation, wear suitable respiratory equipment. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). |
| The product is labelled for supply in accordance with the current issue of CHIP Regulations, and latest version of the approved supply list. |
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| 02/09/1999 |
| The information contained in this MSDS is based on the present state of knowledge and current national legislation. As the specific conditions of use of the product are outside the supplier's control, the user is responsible for ensuring that the requirements of relevant legislation are compiled with. The information in this MSDS provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications. The Environmental Protection (Duty of Care) Regulations 1992 (SI 1992:2839). Further information and relevant advice can be found in: The Control of Substances Hazardous to Health Regulations 1988 (SI1988:1657). The Highly Flammable Liquids and liquefied Petroleum Gases Regulations 197 (SI 1972:917). The Manual Handling Operations Regulations 1992 (SI 1992:2793). Storage of Flammable Liquids in Containers, HS(G)51. Storage of Packaged Dangerous Substances, HS(G)71. The selection, use and maintenance of respiratory protective equipment: A practical guide HS(G)53. |